Two3D-supramolecular coordination polymers (SCP); {[SnMe3(bpe)] [Ag(CN)2].2H2O}, 1 and {[CuI(CN2(phen)CuII(CN)2(phen)].5H2O}, 2 have been synthesized and characterized by physicochemical and spectroscopic methods. The structure of 1 consists of cationic {-Sn(Me3)-bpe-} chains that are neutralized by [Ag(CN)2]- anions. The dicyanoargentate anions present discrete uncoordinated fragments between the cationic chains. The water molecules bind the cationic chains and the anions forming 3D-supramolecular structure through hydrogen bonds. The most intriguing feature in the structure of 2 is the unusual supramolecular interactions, including hydrogen bonds which involve the terminal cyanide and the phenanthroline (phen) ligands and π–π stacking which generate a unique 3D-supramolecular architecture in the solid state. The SCP 1 and2 exhibit good catalytic activity for the formation of substituted triazoles. In this case, the SCP 1 and 2-catalyzed alkyne–azidecycloaddition provide 1,4-disubstituted1,2,3-triazoles with such efficiency and scope that the transformation has been described as “click” chemistry.
Etaiw, S. H., Salem, I., & Tawfik, A. (2017). Silver and copper-Supramolecular coordination polymers catalyzed alkyne–azide “Click” cycloadditions. Delta Journal of Science, 38(2), 161-176. doi: 10.21608/djs.2017.139441
MLA
SafaaEldin H. Etaiw; Ibrahim Salem; Alaa Tawfik. "Silver and copper-Supramolecular coordination polymers catalyzed alkyne–azide “Click” cycloadditions", Delta Journal of Science, 38, 2, 2017, 161-176. doi: 10.21608/djs.2017.139441
HARVARD
Etaiw, S. H., Salem, I., Tawfik, A. (2017). 'Silver and copper-Supramolecular coordination polymers catalyzed alkyne–azide “Click” cycloadditions', Delta Journal of Science, 38(2), pp. 161-176. doi: 10.21608/djs.2017.139441
VANCOUVER
Etaiw, S. H., Salem, I., Tawfik, A. Silver and copper-Supramolecular coordination polymers catalyzed alkyne–azide “Click” cycloadditions. Delta Journal of Science, 2017; 38(2): 161-176. doi: 10.21608/djs.2017.139441
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